Cauchy's equation

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Cauchy's equation is an empirical relationship between the refractive index n and wavelength of light λ for a particular transparent material. It is named for the mathematician Augustin Louis Cauchy, who defined it in 1836.

The most general form of Cauchy's equation is:

<math> n(\lambda) = A + \frac {B}{\lambda^2} + \frac{C}{\lambda^4} + \cdots</math>

where A, B, C, etc., are coefficients (usually quoted for λ in micrometres) that can be determined for a material by fitting the equation to measured refractive indices at known wavelengths.

Usually, it is sufficient to use a two-term form of the equation:

<math> n(\lambda) = A + \frac{B}{\lambda^2}</math>

where A and B are coefficients as before.

A table of coefficients for common optical materials is shown below:

Material	A	B (μm²)
Fused silica	1.4580	0.00354
Borosilicate glass BK7	1.5046	0.00420
Hard crown glass K5	1.5220	0.00459
Barium crown glass BaK4	1.5690	0.00531
Barium flint glass BaF10	1.6700	0.00743
Dense flint glass SF10	1.7280	0.01342

The theory of light-matter interaction on which Cauchy based this equation was later found to be incorrect. In particular, the equation is only valid for regions of normal dispersion in the visible wavelength region. In the infrared, the equation becomes inaccurate, and cannot represent regions of anomalous dispersion. Despite this, its mathematical simplicity makes it useful in some applications.

The Sellmeier equation is a later development of Cauchy's work that handles anomalously dispersive regions, and more accurately models a material's refractive index across the ultraviolet, visible, and infrared spectrum.