Functional group
From Wikipedia, the free encyclopedia
- For other uses, see Functional group (disambiguation).
In organic chemistry, functional groups are specific groups of atoms within molecules, that are responsible for the characteristic chemical reactions of those molecules. The same functional group will undergo the same or similar chemical reaction(s) regardless of the size of the molecule it is a part of.
The following is a list of common functional groups. In the formulas, the symbols R and R' usually denotes an attached hydrogen, or a hydrocarbon side chain of any length, but may sometimes refer to any group of atoms. Below is an image of multiple functional groups found in organic chemistry.
(For convenience, the basic functional groups covered in General Biology are also listed here)
Combining the names of functional groups with the names of the parent alkanes generates a powerful systematic nomenclature for naming organic compounds.
The non-hydrogen atoms of functional groups are always associated with each other and with the rest of the molecule by covalent bonds. When the group of atoms is associated with the rest of the molecule primarily by ionic forces, the group is referred to more properly as a polyatomic ion or complex ion. And all of these are called radicals, by a meaning of the term radical that predates the free radical.
The first carbon after the carbon that attaches to the functional group is called the alpha carbon.
Functional groups are attached to the carbon backbone of organic molecules. They determine the characteristics and chemical reactivity of molecules. Functional groups are far less stable than the carbon backbone and are likely to participate in chemical reactions. Six common biological functional groups are hydrogen, hydroxyl, carboxyl, amino, phosphate, and methyl.
[edit] External links
- IUPAC ligand abbreviations (pdf)
- IUPAC Gold Book (Compendium of Chemical Terminology)
- IUPAC Blue Book (organic nomenclature)
| Functional groups |
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| Chemical class: Alcohol • Aldehyde • Alkane • Alkene • Alkyne • Amide • Amine • Azo compound • Benzene derivative • Carboxylic acid • Cyanate • Ester • Ether • Haloalkane • Imine • Isocyanide • Isocyanate • Ketone • Nitrile • Nitro compound • Nitroso compound • Peroxide • Phosphoric acid • Pyridine derivative • Sulfone • Sulfonic acid • Sulfoxide • Thioether • Thiol • Toluene derivative |
| Topics in organic chemistry |
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Aromaticity | Covalent bonding | Functional groups | Nomenclature | Organic compounds | Organic reactions | Organic synthesis | Publications | Spectroscopy | Stereochemistry |
| List of organic compounds |
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